This work investigates the thermal nonlinear optical properties of norbixin, a natural dye extracted fromBixa orellana L. seeds, dissolved in acetone. The molecular structure and optical response were characterized using UV-Vis, FT-IR, and Raman spectroscopies. The optical band gap was estimated to be2.40 eV using the Tauc plot method, indicating that the excitation at 532 nm (hν = 2.33 eV) occurs in anear-resonant regime. Nonlinear optical properties were investigated using the Z-scan technique and the
analysis of far-field diffraction ring patterns under continuous-wave (CW) laser illumination. Open-aperture Z-scan measurements revealed saturable absorption (SA) behavior, characterized by a negative nonlinear absorption coefficient of while closed-aperture Z-scan showed aclear peak–valley trace indicative of a strong self-defocusing effect, from which a negative nonlinearrefractive index on the order of was determined. A discrepancy of
approximately three orders of magnitude was observed between the nonlinear parameters obtained fromZ-scan and spatial self-phase modulation (SSPM). This difference is discussed in terms of concentration-dependent thermal loading, the presence of large on-axis phase shifts. The transition from a radially symmetric to a vertically compressed diffraction pattern confirms the influence of a convection-dominated regime under high-intensity CW. These results establish norbixin as a promising sustainable nonlinear optical material for photonic applications, including optical limiters and all-optical switches,while providing fundamental insights into thermo-optic effects and convection in nonlinear media.